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On 14/12/2024 4:23 am, john larkin wrote:I guess not many universities offer a PhD in non-physical chemistry these days. :(On Thu, 12 Dec 2024 23:57:54 -0700, Don YThat's what Warburg impedances are about.
<blockedofcourse@foo.invalid> wrote:
>At a fixed time and temperature, is it safe to model a battery as a>
fixed voltage source behind a series resistance? Possibly, additionally,
a parallel RC to cover transients?
>
In particular, does the model need to change based on whether the
battery is being charged or discharged? (i.e., to estimate that
series resistance)
I've wondered about electro-chemical time lags, ions drifting around
in liquids, as in what would the Spice model of some battery be?
AndI've got a Ph.D. in physical chemistry, but batteries are electrochemistry - I know a guy who has just completed a Ph.D. with a thesis on a particular lithium ion battery chemistry. It's a specialised subject.
on a slower time scale, the morphology of a battery changes with time.
Nearly discharged batteries sure go Hi-Z.
>
What we need here is a good physical chemistry guy.
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